Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
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Figure: Co-condensation of boronic acid building blocks (BTBA, BTPA, BPDA) with HHTP to give 2D COFs (COFs-6, -8, and -10) having systematically designed porous structures. COF illustrations are to scale. Coloring scheme: C, gray; H, white; B, orange; O, red.
Reticular chemistry is concerned with linking molecular building
blocks into predetermined periodic structures using strong bonds.1
This chemistry has led to the design and synthesis of new porous
materials for which the composition, structure, metrics, and
functionality can be systematically varied.
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