Picky MOF crystals show promise from Chemistry World
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The use of metal-organic frameworks (MOFs) so far has largely relied on nonspecific binding
interactions to host small molecular guests. We used long organic struts (~2 nanometers) incorporating
34- and 36-membered macrocyclic polyethers as recognition modules in the construction of several
crystalline primitive cubic frameworks that engage in specific binding in a way not observed in passive,
open reticulated geometries.
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